Iron Complexes of <i>N</i> , <i>C</i> -Chelate Ligands toward Catalytic Hydrosilylation of Ketones
turnover frequency and a 80,000 turnover number toward acetophenone reduction by PMHS at room temperature and is compatible with a broad scope of substrates, including the sterically demanding ones. Preliminary studies were conducted to probe the mechanism of the catalysis.
Authors
- Pedro A. Mendez Ocampo
- Qiuming Liang
- Datong Song (ORCID: https://orcid.org/0000-0001-6622-5980)
- Mochi Li
- Jose L. Jimenez Santiago
Institutions
- University of Toronto (CA)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-05-08
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01574
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Canada Foundation for Innovation
- Consejo Nacional de Ciencia y Tecnología
- Natural Sciences and Engineering Research Council of Canada