Spatial and Temporal Variability of Eastern Pacific Radiocarbon and Carbon Chemistry From the Ice Age to Today
Abstract Proxy records of seawater radiocarbon ( 14 C/C) provide strong constraints on how changes in ocean ventilation contributed to the increase in atmospheric CO 2 during the termination of the last ice age (≈18,000‐to‐12,000 years ago). One outstanding problem, however, is the existence of anomalously low deglacial benthic foraminiferal 14 C/C in the intermediate‐depth Eastern Tropical North Pacific (ETNP) near the Gulf of California (GoC). This deglacial ETNP 14 C/C anomaly is hypothesized to reflect either (a) an artifact of the proxy record, (b) the advection of low 14 C/C seawater, or (c) the input of 14 C/C‐depleted geologic carbon related to local seafloor volcanism. To test these hypotheses, we first use new sediment‐trap and seaweed 14 C/C to establish a new baseline understanding of ETNP seawater 14 C/C, which suggest that anomalously low 14 C/C is upwelled in the modern GoC. We then apply new geochemical experiments to test and ultimately validate the utility of the benthic foraminiferal 14 C/C as a proxy for seawater 14 C/C. Finally, we present a compilation of published and new glacial‐interglacial benthic foraminiferal 14 C/C records, specifically developed to map the spatial and temporal variability of the intermediate‐depth water mass containing the deglacial ETNP 14 C/C anomaly. These results clearly show that the ETNP deglacial 14 C/C anomaly develops near the GoC mouth, concomitant with local hydrothermal systems. Considering these results and those of our companion paper (Green et al., 2026, https://doi.org/10.1029/2025pa005217 ), we argue that the input of pH‐neutral geologic carbon from hydrothermal vents near and within the GoC could explain the anomalous intermediate‐depth 14 C/C values both during the deglaciation and today.
Authors
- Eric Tappa (ORCID: https://orcid.org/0000-0002-2142-5820)
- Elsa Arellano‐Torres (ORCID: https://orcid.org/0000-0001-5237-8636)
- Patrick A. Rafter (ORCID: https://orcid.org/0000-0002-6352-7593)
- Mathis P. Hain (ORCID: https://orcid.org/0000-0002-8478-1857)
- I. L. Hendy (ORCID: https://orcid.org/0000-0001-8305-6752)
- Kaustubh Thirumalai (ORCID: https://orcid.org/0000-0002-7875-4182)
- Frank Pavia
- William R. Gray
- James W.B. Rae
- Tim DeVries
- Juan C. Herguera (ORCID: https://orcid.org/0000-0001-8335-2607)
- Ryan A. Green (ORCID: https://orcid.org/0000-0002-2411-8025)
- Maria L. Machain‐Castillo (ORCID: https://orcid.org/0000-0002-4973-4967)
- Martin Soto‐Jimenez (ORCID: https://orcid.org/0000-0001-7584-3684)
- John R. Southon (ORCID: https://orcid.org/0000-0001-6168-6235)
Institutions
- Santa Monica College (US)
- University of Arizona (US)
- University of California, Santa Barbara (US)
- University of South Carolina (US)
- University of St Andrews (GB)
- University of California, Santa Cruz (US)
- University of Washington (US)
- University of California, Irvine (US)
- University of Michigan (US)
- Laboratoire de Mesure du Carbone 14 (FR)
- Centro de Investigación Científica y de Educación Superior de Ensenada (MX)
- University of South Florida St. Petersburg (US)
- Universidad Nacional Autónoma de México (MX)
Publication Details
- Journal
- Paleoceanography and Paleoclimatology
- Published
- 2026-05-01
- DOI
- https://doi.org/10.1029/2025pa005265
- Citations
- 1
- Primary Topic
- Geology and Paleoclimatology Research
- Type
- article
- Field-Weighted Citation Impact
- 20.20
Funders
- National Science Foundation