Spatial and Temporal Variability of Eastern Pacific Radiocarbon and Carbon Chemistry From the Ice Age to Today

Abstract Proxy records of seawater radiocarbon ( 14 C/C) provide strong constraints on how changes in ocean ventilation contributed to the increase in atmospheric CO 2 during the termination of the last ice age (≈18,000‐to‐12,000 years ago). One outstanding problem, however, is the existence of anomalously low deglacial benthic foraminiferal 14 C/C in the intermediate‐depth Eastern Tropical North Pacific (ETNP) near the Gulf of California (GoC). This deglacial ETNP 14 C/C anomaly is hypothesized to reflect either (a) an artifact of the proxy record, (b) the advection of low 14 C/C seawater, or (c) the input of 14 C/C‐depleted geologic carbon related to local seafloor volcanism. To test these hypotheses, we first use new sediment‐trap and seaweed 14 C/C to establish a new baseline understanding of ETNP seawater 14 C/C, which suggest that anomalously low 14 C/C is upwelled in the modern GoC. We then apply new geochemical experiments to test and ultimately validate the utility of the benthic foraminiferal 14 C/C as a proxy for seawater 14 C/C. Finally, we present a compilation of published and new glacial‐interglacial benthic foraminiferal 14 C/C records, specifically developed to map the spatial and temporal variability of the intermediate‐depth water mass containing the deglacial ETNP 14 C/C anomaly. These results clearly show that the ETNP deglacial 14 C/C anomaly develops near the GoC mouth, concomitant with local hydrothermal systems. Considering these results and those of our companion paper (Green et al., 2026, https://doi.org/10.1029/2025pa005217 ), we argue that the input of pH‐neutral geologic carbon from hydrothermal vents near and within the GoC could explain the anomalous intermediate‐depth 14 C/C values both during the deglaciation and today.

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Publication Details

Journal
Paleoceanography and Paleoclimatology
Published
2026-05-01
DOI
https://doi.org/10.1029/2025pa005265
Citations
1
Primary Topic
Geology and Paleoclimatology Research
Type
article
Field-Weighted Citation Impact
20.20

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article

Spatial and Temporal Variability of Eastern Pacific Radiocarbon and Carbon Chemistry From the Ice Age to Today

Eric Tappa, Elsa Arellano‐Torres, Patrick A. Rafter, Mathis P. Hain et al.
1 citations
Paleoceanography and Paleoclimatology
Geology and Paleoclimatology Research
20.20
article

Spatial and Temporal Variability of Eastern Pacific Radiocarbon and Carbon Chemistry From the Ice Age to Today

Eric Tappa, Elsa Arellano‐Torres, Patrick A. Rafter, Mathis P. Hain, I. L. Hendy, Kaustubh Thirumalai, Frank Pavia, William R. Gray, James W.B. Rae, Tim DeVries, Juan C. Herguera, Ryan A. Green, Maria L. Machain‐Castillo, Martin Soto‐Jimenez, John R. Southon
article en
1 citations

Abstract

Abstract Proxy records of seawater radiocarbon ( 14 C/C) provide strong constraints on how changes in ocean ventilation contributed to the increase in atmospheric CO 2 during the termination of the last ice age (≈18,000‐to‐12,000 years ago). One outstanding problem, however, is the existence of anomalously low deglacial benthic foraminiferal 14 C/C in the intermediate‐depth Eastern Tropical North Pacific (ETNP) near the Gulf of California (GoC). This deglacial ETNP 14 C/C anomaly is hypothesized to reflect either (a) an artifact of the proxy record, (b) the advection of low 14 C/C seawater, or (c) the input of 14 C/C‐depleted geologic carbon related to local seafloor volcanism. To test these hypotheses, we first use new sediment‐trap and seaweed 14 C/C to establish a new baseline understanding of ETNP seawater 14 C/C, which suggest that anomalously low 14 C/C is upwelled in the modern GoC. We then apply new geochemical experiments to test and ultimately validate the utility of the benthic foraminiferal 14 C/C as a proxy for seawater 14 C/C. Finally, we present a compilation of published and new glacial‐interglacial benthic foraminiferal 14 C/C records, specifically developed to map the spatial and temporal variability of the intermediate‐depth water mass containing the deglacial ETNP 14 C/C anomaly. These results clearly show that the ETNP deglacial 14 C/C anomaly develops near the GoC mouth, concomitant with local hydrothermal systems. Considering these results and those of our companion paper (Green et al., 2026, https://doi.org/10.1029/2025pa005217 ), we argue that the input of pH‐neutral geologic carbon from hydrothermal vents near and within the GoC could explain the anomalous intermediate‐depth 14 C/C values both during the deglaciation and today.

Paleoceanography and PaleoclimatologyVol. 41(5)
Santa Monica College (US), University of Arizona (US), University of California, Santa Barbara (US), University of South Carolina (US), University of St Andrews (GB), University of California, Santa Cruz (US), University of Washington (US), University of California, Irvine (US), University of Michigan (US), Laboratoire de Mesure du Carbone 14 (FR), Centro de Investigación Científica y de Educación Superior de Ensenada (MX), University of South Florida St. Petersburg (US), Universidad Nacional Autónoma de México (MX)
National Science Foundation
Life below water
Openalex Percentile: Top 1%
Geology and Paleoclimatology Research
20.20
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