Tracing Groundwater Recharge Sources and Controls on Groundwater Quality in a Delineated Aquifer to Support Groundwater Allocation, De Aar, Northern Cape, South Africa

Groundwater-dependent communities such as De Aar require a better understanding of groundwater systems to ensure sustainable allocation. This study aims to trace recharge sources in unconfined and confined aquifers and identify processes controlling groundwater quality using hydrogeochemistry and environmental tracers. It argues that aquifer delineation and hydraulic parameters alone cannot fully identify recharge sources or geochemical processes; integrating them with hydrogeochemistry and environmental tracers provides stronger evidence to support groundwater allocation. To validate the argument, the study integrated hydrogeochemical analysis, stable isotopes, tritium, radon-222, and statistical methods supported by depth-specific groundwater sampling. The results, interpreted using Piper and Gibbs diagrams, PHREEQC modelling, and scatter plots, show that groundwater evolution is mainly controlled by rock–water interaction, ion exchange, evaporation, and mixing processes. Ca–HCO3 water indicates recent recharge, while Na–Cl water reflects evaporation effects in both unconfined and confined aquifers, with halite dissolution contributing to Na and Cl enrichment. Isotope results indicate that unconfined aquifer water is isotopically enriched and linked to recent recharge, whereas confined aquifer and spring waters are depleted, suggesting recharge from higher elevations through fractured zones. Tritium dating reveals young (<30 years), intermediate (30–50 years), and old groundwater (60–109 years), while radon results indicate active groundwater flow path, particularly along fractures. These findings demonstrate that groundwater recharge is derived from both local meteoric sources and regional contributions, resulting in predominantly fresh groundwater; however, localized quality concerns should be considered for improved water allocation.