Graphene Oxide as Valuable Additive for Improving ZnO Electrochemical Properties: Zn/xGO (x = 0, 0.1, and 0.5 wt.%) as Photoelectrocatalysts for Water Splitting and Electrochemical Sensor for Diclofenac

Graphene oxide (GO) was employed as an additive to improve the electrochemical activity of zinc oxide (ZnO) used as both a photoelectrocatalyst for water splitting and an electrochemical sensor for detection of diclofenac. To comprehend the influence of a small amount of GO on the electrochemical activity of ZnO, a series of ZnO/xGO (x = 0, 0.1, and 0.5) particles was synthesized by microwave processing of Zn(OH)2 precipitate in the presence of 0.1 and 0.5 wt.% of previously prepared GO. The phase composition and crystal structure ordering of ZnO/xGO particles were investigated by XRD and Raman spectroscopy. The optical properties were studied by UV–Vis DRS and PL spectroscopy. The particle morphology was inspected by FE–SEM while the textural properties were analyzed by the low-temperature nitrogen adsorption–desorption method. The (photo)electrocatalytic and electrochemical sensing activities were examined on the ZnO/rxGO modified glassy carbon electrodes (GCEs) prepared by in situ reduction of the ZnO/xGO modified GCEs for 120 s. The electro- and photoelectrocatalytic activity of ZnO/rxGO modified GCEs for water splitting was tested in dark conditions and after 60 min under illumination, respectively, employing linear sweep voltammetry in 0.1 M NaOH and 0.1 M H2SO4 as electrolytes. The electrochemical sensing activity of ZnO/rxGO modified GCEs was tested for detection of diclofenac in aqueous solution. The improvement in the electrochemical activity of ZnO was correlated with the added amount of GO, structural defects, and particle morphology.