CF Energy Levels and ZFS Modeling for Mn <sup>2+</sup> : ZnRb <sub>2</sub> (SO <sub>4</sub> ) <sub>2</sub> ·6H <sub>2</sub> O
ABSTRACT The zero field splitting and crystal field (CF) parameters of Mn 2+ ‐doped ZnRb 2 (SO 4 ) 2 ·6H 2 O (ZRS) single crystals are modeled using the superposition model. The parameters thus determined are in conformity with those evaluated from EPR. The experimental EPR result that the Zn 2+ site is occupied by the Mn 2+ ion in ZRS is verified. The crystal's optical spectra are calculated utilizing the above CF parameters and CF analysis program. A fair correspondence is obtained with the experimental crystal‐field energy levels. Thus, the theoretical analysis confirms the experimental observations.
Authors
- Vikram Singh (ORCID: https://orcid.org/0000-0003-3813-586X)
- Maroj Bharati (ORCID: https://orcid.org/0009-0007-8219-0993)
- Ram Kripal (ORCID: https://orcid.org/0000-0002-3483-8704)
Institutions
- University of Allahabad (IN)
- Nehru Gram Bharti University (IN)
Publication Details
- Journal
- Chemical Engineering & Technology
- Published
- 2026-05-01
- DOI
- https://doi.org/10.1002/ceat.70218
- Primary Topic
- Luminescence Properties of Advanced Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00