Comparative impedance analysis of cold sintered and conventionally sintered ZnO-BaTiO <sub>3</sub> composite

In the present work, focusing on ZnO-BaTiO 3 composite, we did a comparative study of cold sintered (400 MPa, 300 °C for 1 h dwell time) and conventionally sintered (1100 °C for 1 h dwell time) samples. Impedance analysis conducted across a temperature range of 25–250 °C and a frequency range of 100 Hz to 1 M Hz, revealed higher grain boundary resistance and space charge in cold sintered samples. Activation energy for alternating conduction mechanism for cold sintered samples (0.22 eV) was calculated to be comparable to that of conventionally sintered samples (0.18 eV). The distinct role of cold sintered samples was explained by the presence of possible charged defects at their grain boundaries.

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Publication Details

Journal
Materials Science and Technology
Published
2026-04-30
DOI
https://doi.org/10.1177/02670836261445351
Primary Topic
Microwave Dielectric Ceramics Synthesis
Type
article
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article

Comparative impedance analysis of cold sintered and conventionally sintered ZnO-BaTiO 3 composite

Khushnuda Nur, Adnan Bajwa, Qamar Hayat, Adnan Maqbool et al.
Materials Science and Technology
Microwave Dielectric Ceramics Synthesis
article

Comparative impedance analysis of cold sintered and conventionally sintered ZnO-BaTiO 3 composite

Khushnuda Nur, Adnan Bajwa, Qamar Hayat, Adnan Maqbool, Muhammad Rafiq, Muhammad Salman Habib, Muhammad Zubaır, Imran Hussain Khan, Abdullah Malik
article en

Abstract

In the present work, focusing on ZnO-BaTiO 3 composite, we did a comparative study of cold sintered (400 MPa, 300 °C for 1 h dwell time) and conventionally sintered (1100 °C for 1 h dwell time) samples. Impedance analysis conducted across a temperature range of 25–250 °C and a frequency range of 100 Hz to 1 M Hz, revealed higher grain boundary resistance and space charge in cold sintered samples. Activation energy for alternating conduction mechanism for cold sintered samples (0.22 eV) was calculated to be comparable to that of conventionally sintered samples (0.18 eV). The distinct role of cold sintered samples was explained by the presence of possible charged defects at their grain boundaries.

Materials Science and Technology
University of Engineering and Technology Lahore (PK), University of Warwick (GB), Sungkyunkwan University (KR)
Affordable and clean energy
Openalex Percentile: Top 10%
Microwave Dielectric Ceramics Synthesis
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Comparative impedance analysis of cold sintered and conventionally sintered ZnO-BaTiO <sub>3</sub> composite — Khushnuda Nur, Adnan Bajwa, et al. · Materials Science and Technology (2026) | TGRS Research Map | TGRS