An Empirical Model of the Kinetics of Hydrogen-Induced Cracking in API 5L Steel: Part 1

An empirical model of the kinetics of Hydrogen-Induced Cracking (HIC) in API 5L steels was derived using the best-fit equation for experimental data obtained from cathodic charging tests. The model represents the growth of both individual and interconnecting cracks, using a double exponential equation known as the Gumbel distribution. Current density was the main independent input variable, as it is related to the hydrogen influx during the cathodic charging experiment. The results indicated that in the initial hours of cathodic charging most of the available HIC nucleation sites are activated, the growth of these individual cracks being the main contribution to the overall kinetics. Further crack growth is due to the interconnection of individual cracks, decreasing the growth rate until it becomes nearly zero. The proposed model is used in a simulation algorithm that accurately describes the complete HIC kinetics, for both short- and long-term hydrogen charging exposure, reproducing the effects of applied current density on the total cracked area and growth rates. Finally, the simulation algorithm adequately predicts the spatial distribution of HIC in a bidimensional plane that emulates the detection of HIC by C-scan ultrasonic inspection.

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Publication Details

Journal
Hydrogen
Published
2026-04-27
DOI
https://doi.org/10.3390/hydrogen7020057
Primary Topic
Hydrogen embrittlement and corrosion behaviors in metals
Type
article
Field-Weighted Citation Impact
0.00

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article

An Empirical Model of the Kinetics of Hydrogen-Induced Cracking in API 5L Steel: Part 1

Dario A. Sigala-Garcia, Héctor J. Dorantes‐Rosales, Manuel Alejandro Beltrán Zúñiga, Gabriel Sepúlveda-Cervantes et al.
Hydrogen
Hydrogen embrittlement and corrosion behaviors in metals
article

An Empirical Model of the Kinetics of Hydrogen-Induced Cracking in API 5L Steel: Part 1

Dario A. Sigala-Garcia, Héctor J. Dorantes‐Rosales, Manuel Alejandro Beltrán Zúñiga, Gabriel Sepúlveda-Cervantes, Suset Santana-Hernández, Diego Israel Rivas-López, Jorge Luis González-Velázquez
article en

Abstract

An empirical model of the kinetics of Hydrogen-Induced Cracking (HIC) in API 5L steels was derived using the best-fit equation for experimental data obtained from cathodic charging tests. The model represents the growth of both individual and interconnecting cracks, using a double exponential equation known as the Gumbel distribution. Current density was the main independent input variable, as it is related to the hydrogen influx during the cathodic charging experiment. The results indicated that in the initial hours of cathodic charging most of the available HIC nucleation sites are activated, the growth of these individual cracks being the main contribution to the overall kinetics. Further crack growth is due to the interconnection of individual cracks, decreasing the growth rate until it becomes nearly zero. The proposed model is used in a simulation algorithm that accurately describes the complete HIC kinetics, for both short- and long-term hydrogen charging exposure, reproducing the effects of applied current density on the total cracked area and growth rates. Finally, the simulation algorithm adequately predicts the spatial distribution of HIC in a bidimensional plane that emulates the detection of HIC by C-scan ultrasonic inspection.

HydrogenVol. 7(2)
Universidad Autónoma de la Ciudad de México (MX), Instituto Politécnico Nacional (MX), Universidad Nacional Autónoma de México (MX)
Instituto Politécnico Nacional
Openalex Percentile: Top 14%
Hydrogen embrittlement and corrosion behaviors in metals
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