Asymmetry of the Ferroelectric Phase Transition in BaTiO <sub>3</sub> (Adv. Mater. 25/2026)

Ferroelectric Phase Transition in BaTiO3 Phase transitions are typically assumed to behave identically in forward and reverse. This work shows that in the ferroelectric material barium titanate this is not true: heating drives an abrupt, first-order jump, while cooling gives a smooth, continuous change. This surprising asymmetry challenges standard classifications of phase transitions and opens new strategies to design novel energy-storage devices. More details can be found in the Research Article by Yachin Ivry and co-workers (DOI: 10.1002/adma.202516507).

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Publication Details

Journal
Advanced Materials
Published
2026-05-01
DOI
https://doi.org/10.1002/adma.73158
Primary Topic
Ferroelectric and Piezoelectric Materials
Type
article
Field-Weighted Citation Impact
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article

Asymmetry of the Ferroelectric Phase Transition in BaTiO 3 (Adv. Mater. 25/2026)

Pravin Kavle, Rajesh Mandal, Yachin Ivry, Maya Barzilay et al.
Advanced Materials
Ferroelectric and Piezoelectric Materials
article

Asymmetry of the Ferroelectric Phase Transition in BaTiO 3 (Adv. Mater. 25/2026)

Pravin Kavle, Rajesh Mandal, Yachin Ivry, Maya Barzilay, Neus Domingo, Ignacio J. Villar‐García, Asaf Hershkovitz, David Spirito, Jamil Tanus, Semen Gorfman, Elangovan Hemaprabha, Long‐Qing Chen, Bo Wang, Lane W. Martin, Ching‐Che Lin
article en

Abstract

Ferroelectric Phase Transition in BaTiO3 Phase transitions are typically assumed to behave identically in forward and reverse. This work shows that in the ferroelectric material barium titanate this is not true: heating drives an abrupt, first-order jump, while cooling gives a smooth, continuous change. This surprising asymmetry challenges standard classifications of phase transitions and opens new strategies to design novel energy-storage devices. More details can be found in the Research Article by Yachin Ivry and co-workers (DOI: 10.1002/adma.202516507).

Advanced MaterialsVol. 38(25)
Lawrence Livermore National Laboratory (US), Oak Ridge National Laboratory (US), Pennsylvania State University (US), Lawrence Berkeley National Laboratory (US), Tel Aviv University (IL), Technion – Israel Institute of Technology (IL), Indian Institute of Technology Madras (IN), Wolfson Medical Center (IL), ALBA Synchrotron (Spain) (ES), Institut Català de Nanociència i Nanotecnologia (ES), Rice University (US), University of California, Berkeley (US)
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Ferroelectric and Piezoelectric Materials
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