Crystal structure and Hirshfeld surface analysis of 10-(3-benzylthiophen-2-yl)-5,5-difluoro-5 <i>H</i> -4λ <sup>4</sup> ,5λ <sup>4</sup> -dipyrrolo[1,2- <i>c</i> :2′,1′- <i>f</i> ][1,3,2]diazaborinine
(21) ring motifs around a mol-ecule, resulting in layers parallel to the (101) plane. The mol-ecules further form layers parallel to the (101) plane through C-H⋯π inter-actions. According to a Hirshfeld surface analysis, H⋯H (41.5%), C⋯H/H⋯C (23.5%) and F⋯H/H⋯F (18.2%) inter-actions are the most significant contributors to the crystal packing.
Authors
- Gizachew Mulugeta Manahelohe (ORCID: https://orcid.org/0000-0002-6098-9450)
- Khudayar I. Hasanov
- Victor N. Khrustalev (ORCID: https://orcid.org/0000-0001-8806-2975)
- Zlata A. Polianskaia (ORCID: https://orcid.org/0009-0006-8392-7283)
- Narmina A. Guliyeva (ORCID: https://orcid.org/0009-0006-4571-9520)
- Artem S. Larionov (ORCID: https://orcid.org/0009-0000-3217-2833)
- Mehmet Akkurt (ORCID: https://orcid.org/0000-0003-2421-0929)
Institutions
- Peoples' Friendship University of Russia (RU)
- Azerbaijan Medical University (AZ)
- Russian New University (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
- Baku Engineering University (AZ)
- University of Gondar (ET)
- Erciyes University (TR)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2026-04-14
- DOI
- https://doi.org/10.1107/s2056989026003889
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- RUDN University