Copper-Catalyzed Enantioselective Protoboration of α-Substituted <i>tert</i> -Butyl Acrylates

-butyl ester group is essential for achieving high enantioselectivity. This methodology has been successfully scaled up to the one-gram level and applied to diverse stereoselective derivatizations.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2026-04-30
DOI
https://doi.org/10.1021/acs.joc.6c00629
Primary Topic
Organoboron and organosilicon chemistry
Type
article
Field-Weighted Citation Impact
0.00

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article

Copper-Catalyzed Enantioselective Protoboration of α-Substituted tert -Butyl Acrylates

Tongyu Xu, Fanlong Zeng, Jingwen Huang, Wenbo Qi et al.
The Journal of Organic Chemistry
Organoboron and organosilicon chemistry
article

Copper-Catalyzed Enantioselective Protoboration of α-Substituted tert -Butyl Acrylates

Tongyu Xu, Fanlong Zeng, Jingwen Huang, Wenbo Qi, Xuedi Ma, Yaxi Li
article en

Abstract

-butyl ester group is essential for achieving high enantioselectivity. This methodology has been successfully scaled up to the one-gram level and applied to diverse stereoselective derivatizations.

The Journal of Organic Chemistry
Ministry of Education of the People's Republic of China (CN), Northwest University (CN), Shaanxi Coal Chemical Industry Technology Research Institute (CN)
Key Science and Technology Program of Shaanxi Province
Openalex Percentile: Top 13%
Organoboron and organosilicon chemistry
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