Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of <i>n</i> ‐Pentene

, whereas extra-framework aluminum oxide promotes reactivity by entropically shifting the transition state to a later stage. Together, these results establish alkene cracking in zeolites as an enthalpy-entropy-controlled process dictated by topology and local chemical environment.

Authors

Stefan Schallmoser
Ruixue Zhao (ORCID: https://orcid.org/0000-0001-7251-5423)
Johannes A. Lercher (ORCID: https://orcid.org/0000-0002-2495-1404)
Gary L. Haller (ORCID: https://orcid.org/0000-0001-8482-5488)
Maricruz Sanchez‐Sanchez (ORCID: https://orcid.org/0000-0002-3769-9623)

Institutions

TU Wien (AT)
Yale University (US)
Vienna Biocenter (AT)
Technical University of Munich (DE)

Publication Details

Journal: Angewandte Chemie International Edition
Published: 2026-04-30
DOI: https://doi.org/10.1002/anie.4217298
Primary Topic: Zeolite Catalysis and Synthesis
Type: article
Field-Weighted Citation Impact: 0.00

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article

Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n ‐Pentene

Stefan Schallmoser, Ruixue Zhao, Johannes A. Lercher, Gary L. Haller et al.

Apr 30, 2026

Angewandte Chemie International Edition

Zeolite Catalysis and Synthesis

article

Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n ‐Pentene

Stefan Schallmoser, Ruixue Zhao, Johannes A. Lercher, Gary L. Haller, Maricruz Sanchez‐Sanchez

April 30, 2026article en

Abstract

, whereas extra-framework aluminum oxide promotes reactivity by entropically shifting the transition state to a later stage. Together, these results establish alkene cracking in zeolites as an enthalpy-entropy-controlled process dictated by topology and local chemical environment.

Angewandte Chemie International Edition

TU Wien (AT), Yale University (US), Vienna Biocenter (AT), Technical University of Munich (DE)

Openalex Percentile: Top 16%

Zeolite Catalysis and Synthesis

DOI Open Access PDF OpenAlex

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Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of <i>n</i> ‐Pentene — Stefan Schallmoser, Ruixue Zhao, et al. · Angewandte Chemie International Edition (2026) | TGRS Research Map | TGRS