Organophotocatalytic Radical Chloro-fluorosulfonylation of Alkynyl Cyclohexadienones
Cl using organic dye eosin Y as the photocatalyst is reported. The reaction proceeds smoothly with excellent stereoselectivity via atom transfer radical addition to afford multifunctionalized bicyclic alkenyl sulfonyl fluorides. Downstream reactions of the resulting bicyclic products showcase an efficient approach to access diverse functionalized sulfonyl fluorides from readily available phenols.
Authors
- Chao Kong (ORCID: https://orcid.org/0000-0001-9730-1843)
- Shenlin Huang
- Tianyu He
- Zi Yang
- Yucai Tang
Institutions
- Changsha Medical University (CN)
- Nanjing Forestry University (CN)
- Hunan University of Arts and Science (CN)
- Nomura Plating (Japan) (JP)
Publication Details
- Journal
- Organic Letters
- Published
- 2026-04-30
- DOI
- https://doi.org/10.1021/acs.orglett.6c01403
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Scientific Research Foundation of Hunan Provincial Education Department