Interest and Limitations of Core–Shell Shaping of Heterolanthanide-Based Coordination Polymers

stands for benzene-1,4-dicarboxylate) have been successfully used as luminescent markers for materials traceability. Interest and limitations of core-shell shaping are highlighted. Indeed, on the one hand, it paves the road to new potential applications that are impossible to address with classical molecular alloys, and on the other hand, intrinsic constraints make them irrelevant for other applications. Additionally, this study shows that the interest of the core-shell shaping highly depends on the intermetallic energy transfer and, therefore, on the donor-acceptor pairs that are involved.

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Publication Details

Journal
Inorganic Chemistry
Published
2026-04-30
DOI
https://doi.org/10.1021/acs.inorgchem.6c01155
Primary Topic
Metal-Organic Frameworks: Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Interest and Limitations of Core–Shell Shaping of Heterolanthanide-Based Coordination Polymers

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Interest and Limitations of Core–Shell Shaping of Heterolanthanide-Based Coordination Polymers

Chloé Blais, Kévin Bernot, Guillaume Calvez, Thibaut Morvan, François Le Natur, Aurélien Chang, Carole Daiguebonne, Yan Suffren, Olivier Guillou, Margaux Blunt
article en

Abstract

stands for benzene-1,4-dicarboxylate) have been successfully used as luminescent markers for materials traceability. Interest and limitations of core-shell shaping are highlighted. Indeed, on the one hand, it paves the road to new potential applications that are impossible to address with classical molecular alloys, and on the other hand, intrinsic constraints make them irrelevant for other applications. Additionally, this study shows that the interest of the core-shell shaping highly depends on the intermetallic energy transfer and, therefore, on the donor-acceptor pairs that are involved.

Inorganic ChemistryVol. 65(18)
Centre National de la Recherche Scientifique (FR), Institut Universitaire de France (FR), Institut National des Sciences Appliquées de Rennes (FR), Institut des Sciences Chimiques de Rennes (FR), Olnica (France) (FR), Université de Rennes (FR)
Association Nationale de la Recherche et de la Technologie
Openalex Percentile: Top 20%
Metal-Organic Frameworks: Synthesis and Applications
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