Generalization of the two-diode IV model for background-doped thermophotonic LEDs
In recent work, shifted-junction LEDs were developed that yield extremely low non-radiative losses. However, their IV curves show features that standard two-diode models cannot explain. In this work, these features are described using a generalization of the two-diode model that employs a non-radiative current starting at an ideality factor n i d = 1 , that saturates to n i d = 2 behavior beyond a threshold voltage. This saturating diode (SD) model works particularly well for IV curves that show neither a clear n i d = 1 or n i d = 2 regime. The SD model is verified using drift–diffusion simulations and measured IV curves of shifted-junction LEDs. Subsequently, this framework is applied to establish the radiative current and coupling efficiency required to reach wall-plug efficiencies surpassing unity, which is required for electroluminescent cooling. Specifically, it is demonstrated that the device parameters required to reach the cooling regime have all been achieved separately, albeit in different devices, assuming the radiative current changes in line with what is expected at high light extraction efficiencies from previous numerical studies. • Dark IV behavior is observed that cannot be explained with standard fitting models. • A general IV model is derived that takes doping and barriers into account. • The model fits well with drift–diffusion calculations and experimental data. • Guidelines are presented for demonstrating electroluminescent cooling. • All thresholds for electroluminescent cooling are already met in different devices.
Authors
- J.J. Schermer (ORCID: https://orcid.org/0000-0002-6004-7906)
- Jasper van Gastel (ORCID: https://orcid.org/0009-0009-4255-2632)
- Natasha Gruginskie (ORCID: https://orcid.org/0000-0001-6571-0538)
- Benoît Behaghel (ORCID: https://orcid.org/0000-0003-4629-8028)
- Seyed Ahmad Shahahmadi (ORCID: https://orcid.org/0000-0002-8320-1793)
- Pyry Kivisaari (ORCID: https://orcid.org/0000-0001-8434-3438)
- Jani Oksanen
- Elias Vlieg (ORCID: https://orcid.org/0000-0002-1343-4102)
- Luc van der Krabben (ORCID: https://orcid.org/0000-0002-0494-4231)
Institutions
- Radboud University Nijmegen (NL)
- Aalto University (FI)
Publication Details
- Journal
- Solar Energy Materials and Solar Cells
- Published
- 2026-04-28
- DOI
- https://doi.org/10.1016/j.solmat.2026.114398
- Primary Topic
- Optical properties and cooling technologies in crystalline materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- H2020 European Research Council