Graphene Oxide-Stabilized Polymeric Nanofluids for Enhanced Oil Recovery

Developing advanced nanofluids with tailored rheological properties is crucial for optimizing enhanced oil recovery (EOR) techniques. This study investigates graphene oxide (GO) nanosheet-assisted polymeric nanofluids and evaluates their potential for EOR applications. GO nanosheets were synthesized using the modified Hummers method and characterized using FTIR, UV spectroscopy, XRD, and Raman spectroscopy analysis. Polymeric nanofluids were formulated by dispersing GO nanosheets into hydroxyethyl cellulose (HEC) solutions, and their rheological properties were evaluated at varying shear rates and temperatures to simulate reservoir conditions. The results showed that the addition of a low concentration of GO (50 ppm) significantly enhanced the rheological properties of HEC polymer solutions due to synergistic interactions between GO nanosheets and polymer chains that form three-dimensional networks via hydrogen bonding. These intermolecular interactions were further validated through FTIR and DSC analyses. Additionally, qualitative changes in the sandstone rock’s wettability were evaluated using spectroscopic techniques, revealing a shift toward more water-wet conditions. Core flooding experiments demonstrated superior performance of the polymeric nanofluid, achieving a tertiary oil recovery of 24.76% OOIP compared to 17.93% for polymer flooding. Furthermore, preliminary industrial feasibility and economic analyses suggest the scalability and cost-effectiveness of the developed system. Overall, this study highlights the potential of GO–HEC nanofluids as efficient and viable EOR agents.

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Publication Details

Journal
Energy & Fuels
Published
2026-04-28
DOI
https://doi.org/10.1021/acs.energyfuels.6c00569
Primary Topic
Enhanced Oil Recovery Techniques
Type
article
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article

Graphene Oxide-Stabilized Polymeric Nanofluids for Enhanced Oil Recovery

Nilanjan Pal, G Rao, Ajay Mandal
Energy & Fuels
Enhanced Oil Recovery Techniques
article

Graphene Oxide-Stabilized Polymeric Nanofluids for Enhanced Oil Recovery

Nilanjan Pal, G Rao, Ajay Mandal
article en

Abstract

Developing advanced nanofluids with tailored rheological properties is crucial for optimizing enhanced oil recovery (EOR) techniques. This study investigates graphene oxide (GO) nanosheet-assisted polymeric nanofluids and evaluates their potential for EOR applications. GO nanosheets were synthesized using the modified Hummers method and characterized using FTIR, UV spectroscopy, XRD, and Raman spectroscopy analysis. Polymeric nanofluids were formulated by dispersing GO nanosheets into hydroxyethyl cellulose (HEC) solutions, and their rheological properties were evaluated at varying shear rates and temperatures to simulate reservoir conditions. The results showed that the addition of a low concentration of GO (50 ppm) significantly enhanced the rheological properties of HEC polymer solutions due to synergistic interactions between GO nanosheets and polymer chains that form three-dimensional networks via hydrogen bonding. These intermolecular interactions were further validated through FTIR and DSC analyses. Additionally, qualitative changes in the sandstone rock’s wettability were evaluated using spectroscopic techniques, revealing a shift toward more water-wet conditions. Core flooding experiments demonstrated superior performance of the polymeric nanofluid, achieving a tertiary oil recovery of 24.76% OOIP compared to 17.93% for polymer flooding. Furthermore, preliminary industrial feasibility and economic analyses suggest the scalability and cost-effectiveness of the developed system. Overall, this study highlights the potential of GO–HEC nanofluids as efficient and viable EOR agents.

Energy & FuelsVol. 40(18)
Indian Institute of Technology Dhanbad (IN), University of Petroleum (ID), Indian Institute of Petroleum (IN)
Industry, innovation and infrastructure
Openalex Percentile: Top 16%
Enhanced Oil Recovery Techniques
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Graphene Oxide-Stabilized Polymeric Nanofluids for Enhanced Oil Recovery — Nilanjan Pal, G Rao, et al. · Energy & Fuels (2026) | TGRS Research Map | TGRS