Femtosecond Soft X-ray Absorption Spectroscopy Identifies Metal-Centered S <sub>1</sub> Excited State of Cyanocobalamin

state is primarily an MC excited state. The sub-20 μOD detection sensitivity achieved in this study demonstrates the possibility of applying this method to a wide range of naturally occurring and synthetic transition metal complexes.

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Publication Details

Journal
Journal of the American Chemical Society
Published
2026-04-27
DOI
https://doi.org/10.1021/jacs.6c01860
Primary Topic
Porphyrin Metabolism and Disorders
Type
article
Field-Weighted Citation Impact
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article

Femtosecond Soft X-ray Absorption Spectroscopy Identifies Metal-Centered S 1 Excited State of Cyanocobalamin

Luigi Adriano, D. Lomidze, Yi–Ping Chang, Joana Valério et al.
Journal of the American Chemical Society
Porphyrin Metabolism and Disorders
article

Femtosecond Soft X-ray Absorption Spectroscopy Identifies Metal-Centered S 1 Excited State of Cyanocobalamin

Luigi Adriano, D. Lomidze, Yi–Ping Chang, Joana Valério, Cyril Danilevski, Nahid Ghodrati, Benjamin E. Van Kuiken, Cammille Carinan, Martin Teichmann, Roseanne J. Sension, Robert Carley, Alivia Mukherjee, Talgat Mamyrbayev, Samuel M. Berry, Manuel Harder, Taylor P. McClain, Ru‐Pan Wang, Nils Huse, Ryan M. Lamb, M. Porro, Monica Turcato, David Hammer, Natalia Gerasimova, Robin Engel, Loïc Le Guyader, James E. Penner-Hahn, Andreas Scherz, Zhong Yin, Christian David
article en

Abstract

state is primarily an MC excited state. The sub-20 μOD detection sensitivity achieved in this study demonstrates the possibility of applying this method to a wide range of naturally occurring and synthetic transition metal complexes.

Journal of the American Chemical Society
Ca' Foscari University of Venice (IT), Universität Hamburg (DE), Tohoku University (JP), University of Michigan (US), Deutsches Elektronen-Synchrotron DESY (DE), Paul Scherrer Institute (CH), Center for Free-Electron Laser Science (DE), European X-Ray Free-Electron Laser (DE)
Openalex Percentile: Top 11%
Porphyrin Metabolism and Disorders
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