Enhanced elastocaloric cooling beyond Clausius–Clapeyron limits
and a material coefficient of performance of 4.6, demonstrating competitive cooling performance at practical operating conditions. In addition, the elastocaloric response is maintained over the entire temperature range despite the expected decrease in entropy change at lower temperatures, indicating that the conventional trade-off between temperature span and cooling strength is effectively mitigated. This exceptional behavior originates from a combination of anomalous temperature dependence of the critical stress for martensitic transformation and high mechanical strength, which together enable fully reversible stress-induced transformations across a broad thermal domain. Our findings reveal a new regime of elastocaloric behavior and establish a guiding principle for overcoming the apparent limitations imposed by Clausius-Clapeyron-based descriptions in caloric materials.
Authors
- Sheng Xu (ORCID: https://orcid.org/0000-0002-5299-6642)
- Toshihiro Omori (ORCID: https://orcid.org/0000-0001-9174-0239)
- Ryoji Kiyanagi (ORCID: https://orcid.org/0000-0002-8636-1258)
- Takuro Kawasaki (ORCID: https://orcid.org/0000-0002-1878-6799)
- Yoshihisa Ishikawa (ORCID: https://orcid.org/0000-0002-0437-3088)
- Yuxin Song (ORCID: https://orcid.org/0009-0009-2437-2283)
- Ryosuke Kainuma
Institutions
- Japan Atomic Energy Agency (JP)
- Tohoku University (JP)
- Japan Proton Accelerator Research Complex (JP)
- Comprehensive Research Organization for Science and Society (JP)
Publication Details
- Journal
- Nature Communications
- Published
- 2026-04-27
- DOI
- https://doi.org/10.1038/s41467-026-72172-7
- Primary Topic
- Shape Memory Alloy Transformations
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Environmental Restoration and Conservation Agency
- Materials and Life Science Experimental Facility
- Ministry of the Environment, Government of Japan
- Japan Society for the Promotion of Science