Paradigm Shift in Mechanistic Understanding and Catalyst Design for Heterogeneous Ethylene Methoxycarbonylation
catalyst shows over 80 times higher activity than Ru nanocatalysts and 6 times that of Pt single-atom catalysts. It also demonstrates exceptional stability over 180 h, with a turnover number exceeding 200,000, surpassing all known heterogeneous ethylene methoxycarbonylation catalysts and rivaling Pd catalysts.
Authors
- Haozhi Zhou
- Shunan Zhang (ORCID: https://orcid.org/0000-0002-2385-0767)
- Hui Wang (ORCID: https://orcid.org/0000-0002-6536-5188)
- Ruonan Zhang (ORCID: https://orcid.org/0000-0003-0030-6758)
- Shenggang Li (ORCID: https://orcid.org/0000-0002-5173-0025)
- Hao Liang (ORCID: https://orcid.org/0000-0002-5709-2634)
- Hu Luo
- Yuhan Sun
- Yuli Lai
- Hanwen Ji
- Lin Xia
- Xiaofang Liu
Institutions
- Chinese Academy of Sciences (CN)
- ShanghaiTech University (CN)
- Shanghai Advanced Research Institute (CN)
- National Institute of Clean and Low-Carbon Energy (CN)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-04-27
- DOI
- https://doi.org/10.1021/jacs.6c01740
- Primary Topic
- Catalysis and Oxidation Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00