Active Site Engineering of Mn‐Doped CeO <sub>2</sub> Nanozymes: Enhanced Reactivity and Specificity for Colorimetric Detection of Perfluorooctanoic Acid in Waters

redox ratio-enhancing peroxidase-like activity-but also modulates the charge density at metal centers. This electronic regulation strengthens PFOA binding through synergistic electrostatic attraction, Ce─F coordination, and hydrophobic interactions. The colorimetric system was integrated with smartphone-based grayscale analysis, enabling rapid on-site detection of PFOA across diverse real water samples and food matrices, with high recovery rates (93.10-106.75%) and reliable self-calibration. This work provides a facile and robust strategy for mapping PFOA distribution in natural waters.

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Publication Details

Journal
Small
Published
2026-04-26
DOI
https://doi.org/10.1002/smll.202513888
Primary Topic
Advanced Nanomaterials in Catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

Active Site Engineering of Mn‐Doped CeO 2 Nanozymes: Enhanced Reactivity and Specificity for Colorimetric Detection of Perfluorooctanoic Acid in Waters

Han‐Qing Yu, Guang‐feng Wang, Shuang Li, Ming‐Zheng Gu et al.
Small
Advanced Nanomaterials in Catalysis
article

Active Site Engineering of Mn‐Doped CeO 2 Nanozymes: Enhanced Reactivity and Specificity for Colorimetric Detection of Perfluorooctanoic Acid in Waters

Han‐Qing Yu, Guang‐feng Wang, Shuang Li, Ming‐Zheng Gu, Ze‐Xun Xu, Yin‐Bo Ban, Chen‐Fei Li
article en

Abstract

redox ratio-enhancing peroxidase-like activity-but also modulates the charge density at metal centers. This electronic regulation strengthens PFOA binding through synergistic electrostatic attraction, Ce─F coordination, and hydrophobic interactions. The colorimetric system was integrated with smartphone-based grayscale analysis, enabling rapid on-site detection of PFOA across diverse real water samples and food matrices, with high recovery rates (93.10-106.75%) and reliable self-calibration. This work provides a facile and robust strategy for mapping PFOA distribution in natural waters.

Small
University of Science and Technology of China (CN), Anhui Normal University (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 10%
Advanced Nanomaterials in Catalysis
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