Overcoming Kinetic Inertness via Transmetalation: Nickel-Mediated Synthesis of Sulfonamide-Functionalized Pd <sup>II</sup> and Pt <sup>II</sup> Dithiocarbamates
C ligands (L). X-ray crystallographic analysis of 19 structures revealed characteristic inequivalent C-S bond lengths (averaging 1.76 Å vs 1.71 Å across all structures) and partial C-N double bond character, consistent with significant contributions from both dithiocarbamate and thioureide resonance structures. This work provides a general and scalable route to sulfonamide-functionalized Group 10 metal dithiocarbamate complexes that cannot be accessed by direct methods.
Authors
- Лев Е. Зеленков (ORCID: https://orcid.org/0000-0001-6387-7553)
- Nadezhda A. Bokach (ORCID: https://orcid.org/0000-0001-8692-9627)
- Vadim Yu. Kukushkin (ORCID: https://orcid.org/0000-0002-2253-085X)
- Sergey V. Baykov (ORCID: https://orcid.org/0000-0002-8912-5816)
- Павел Сергеевич Постников (ORCID: https://orcid.org/0000-0001-9713-1290)
- Matvey K. Shurikov (ORCID: https://orcid.org/0009-0008-4058-0878)
- Eugene V. Ignatov (ORCID: https://orcid.org/0009-0003-1573-4963)
Institutions
- Altai State University (RU)
- St Petersburg University (RU)
- National Research Tomsk State University (RU)
- Harbin Institute of Technology (CN)
- Tomsk Polytechnic University (RU)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-24
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c00811
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation