Generalizing Pore-Space Partitioning in Metal–Organic Frameworks

) systems. This work results not only in the discovery of new topologies not known before, but also the experimental realization of topologies that had previously existed only as theoretical predictions. Collectively, this work establishes retro-PSP as a generalizable approach for extending PSP to include either more partition modes or more MOF platforms, resulting in new PSP-enabled materials with enhanced stability and tunable gas adsorption properties.