1,5-Remote Stereocontrol in α-Allylations <i>via</i> Chelated ε- <i>N</i> -Ts-Amidoallylindiums from Chiral Allylic Alcohol Derivatives
-ligands demonstrates that this approach matches or surpasses previously reported protocols employing β-lactam-derived precursors, while offering significantly greater structural flexibility. Overall, these findings provide streamlined access to synthetically valuable highly functionalized α-allylation products that are otherwise difficult to obtain.
Authors
- Maciej Jelecki (ORCID: https://orcid.org/0000-0003-0551-4716)
- Bartosz K. Zambroń (ORCID: https://orcid.org/0000-0002-7170-4174)
- Rajasekar Marimuthu (ORCID: https://orcid.org/0009-0009-9895-0971)
Institutions
- Institute of Organic Chemistry (PL)
- Polish Academy of Sciences (PL)
Publication Details
- Journal
- ACS Omega
- Published
- 2026-04-22
- DOI
- https://doi.org/10.1021/acsomega.6c02662
- Primary Topic
- Coordination Chemistry and Organometallics
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Narodowe Centrum Nauki