The ideal gas with a harmonic piston and the constant pressure-to-volume ratio ensemble

We consider an ideal gas enclosed in a vessel with a freely moving piston coupled to an ideal spring. In this model, the gas pressure and volume are proportional to each other, with a constant of proportionality depending on the spring constant. To demonstrate its usefulness at a variety of levels in the physics curriculum, we study this system by employing three approaches of increasing complexity: elementary thermal physics, thermodynamic potentials, and statistical mechanics. In particular, we calculate the system's heat capacity at constant P/V in several ways.

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Publication Details

Journal
American Journal of Physics
Published
2026-04-22
DOI
https://doi.org/10.1119/5.0208569
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
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article

The ideal gas with a harmonic piston and the constant pressure-to-volume ratio ensemble

F. Q. Potiguar
American Journal of Physics
Advanced Thermodynamics and Statistical Mechanics
article

The ideal gas with a harmonic piston and the constant pressure-to-volume ratio ensemble

F. Q. Potiguar
article en

Abstract

We consider an ideal gas enclosed in a vessel with a freely moving piston coupled to an ideal spring. In this model, the gas pressure and volume are proportional to each other, with a constant of proportionality depending on the spring constant. To demonstrate its usefulness at a variety of levels in the physics curriculum, we study this system by employing three approaches of increasing complexity: elementary thermal physics, thermodynamic potentials, and statistical mechanics. In particular, we calculate the system's heat capacity at constant P/V in several ways.

American Journal of PhysicsVol. 94(5)
Universidade Federal do Pará (BR)
Affordable and clean energy
Openalex Percentile: Top 9%
Advanced Thermodynamics and Statistical Mechanics
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