Controlled N-Substitution of a B(8)-Ammonium Cobalt Bis-Dicarbollide
] were optimized using dimethyl sulfate, a suitable solvent, and a base. All compounds were characterized by nuclear magnetic resonance spectroscopy, high-performance liquid chromatography, mass spectrometry, ultraviolet-visible spectroscopy, thin-layer chromatography, melting point, and elemental analysis, and the structure of the trimethylated derivative was confirmed by single-crystal X-ray diffraction.
Authors
- Pavel Kaule (ORCID: https://orcid.org/0000-0002-2041-4919)
- Jan Čejka (ORCID: https://orcid.org/0000-0002-5925-6217)
- Václav Šícha (ORCID: https://orcid.org/0000-0003-3163-1764)
- Viktor Greguš (ORCID: https://orcid.org/0009-0003-5424-3470)
Institutions
- Jan Evangelista Purkyně University in Ústí nad Labem (CZ)
- University of Chemistry and Technology, Prague (CZ)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-22
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c00794
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- European Commission
- Ministerstvo Školství, Mládeže a Tělovýchovy
- Univerzite Jan Evangelista Purkyne v Ústí nad Labem
- Ministerstvo Životního Prostředí