Subzero Conductivity in Antifreeze-Free Ionic Gels from Liquid Crystalline Cellulose−Protein Networks

mediated ionic coordination, (iii) protein-based covalent crosslinking, and (iv) hydrogen bonding and supramolecular assembly within the ionic liquid, resulting in a homogeneous and highly conductive gel. Notably, the immobilization of LC units in the isotropic phase enhances local structural order and elasticity without compromising conductivity. This work pioneers an environmentally benign, mostly bioderived, antifreeze-free ionic gel platform for applications in soft electronics, cryogenic energy devices, deep-sea and space technologies, and biomedical cryo-preservation.

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Publication Details

Journal
ACS Applied Bio Materials
Published
2026-04-22
DOI
https://doi.org/10.1021/acsabm.6c00234
Primary Topic
Ionic liquids properties and applications
Type
article
Field-Weighted Citation Impact
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article

Subzero Conductivity in Antifreeze-Free Ionic Gels from Liquid Crystalline Cellulose−Protein Networks

Challa V. Kumar, Haotian Long, Ankarao Kalluri, Reuben Bosire et al.
ACS Applied Bio Materials
Ionic liquids properties and applications
article

Subzero Conductivity in Antifreeze-Free Ionic Gels from Liquid Crystalline Cellulose−Protein Networks

Challa V. Kumar, Haotian Long, Ankarao Kalluri, Reuben Bosire, Dennis Ndaya, Francis K. Masese, Rajeswari M. Kasi, Chinedum Osuji, Patrick Njenga, Akram Alhadainy
article en

Abstract

mediated ionic coordination, (iii) protein-based covalent crosslinking, and (iv) hydrogen bonding and supramolecular assembly within the ionic liquid, resulting in a homogeneous and highly conductive gel. Notably, the immobilization of LC units in the isotropic phase enhances local structural order and elasticity without compromising conductivity. This work pioneers an environmentally benign, mostly bioderived, antifreeze-free ionic gel platform for applications in soft electronics, cryogenic energy devices, deep-sea and space technologies, and biomedical cryo-preservation.

ACS Applied Bio MaterialsVol. 9(9)
California University of Pennsylvania (US)
Responsible consumption and production
Openalex Percentile: Top 25%
Ionic liquids properties and applications
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