Distance-Dependent, Rate-Accelerating and Diastereoselective Directing Effects in Decatungstate-Mediated Stereoediting Reactions
-configured starting materials. The discovery that noncovalent interactions can be used to guide the reactivity of excited-state DT fundamentally transforms our understanding of this reagent's control paradigms, opening the door to the design of new strategies to tune the selectivity of DT-mediated HAT steps.
Authors
- Alison E. Wendlandt (ORCID: https://orcid.org/0000-0003-2970-9817)
- Leon Wang
- Huiming Liang
- Jin Zhu
Institutions
- Massachusetts Institute of Technology (US)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-04-21
- DOI
- https://doi.org/10.1021/jacs.5c22842
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Institute of General Medical Sciences