A Neutral Linear Cobalt(I) Silylamide as a Platform for Alkyne Cyclotrimerization and an Intermediate‐Spin Imido Cobalt Complex

The synthesis of neutral linear cobalt(I) silylamides is reported. Their use as precatalyst in alkyne cyclotrimerisation and for the formation of an intermediate‐spin imido cobalt complex is explored.

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Publication Details

Journal
Zeitschrift für anorganische und allgemeine Chemie
Published
2026-04-21
DOI
https://doi.org/10.1002/zaac.70128
Primary Topic
Organometallic Complex Synthesis and Catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

A Neutral Linear Cobalt(I) Silylamide as a Platform for Alkyne Cyclotrimerization and an Intermediate‐Spin Imido Cobalt Complex

C. Gunnar Werncke, Andres Gonzalez
Zeitschrift für anorganische und allgemeine Chemie
Organometallic Complex Synthesis and Catalysis
article

A Neutral Linear Cobalt(I) Silylamide as a Platform for Alkyne Cyclotrimerization and an Intermediate‐Spin Imido Cobalt Complex

C. Gunnar Werncke, Andres Gonzalez
article en

Abstract

The synthesis of neutral linear cobalt(I) silylamides is reported. Their use as precatalyst in alkyne cyclotrimerisation and for the formation of an intermediate‐spin imido cobalt complex is explored.

Zeitschrift für anorganische und allgemeine Chemie
Philipps University of Marburg (DE), Leipzig University (DE)
Deutsche Forschungsgemeinschaft
Openalex Percentile: Top 12%
Organometallic Complex Synthesis and Catalysis
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