Redox Modulation and Diffusion Kinetics in Ni-Doped CuO: Insights from Quantum-Inspired Electrochemical Methods
-Window Linear Discharge (R2WLD) method to segment GCD curves and extract linear and pseudocapacitive discharge regions with high fidelity. Additionally, nonlinear Kernel Principal Component Analysis (KPCA) was employed to classify electrochemical regimes based on scan rate behavior. To interpret the evolution of discharge symmetry, a 1D Ising model was adapted to model energetic state transitions under increasing perturbation. These findings underscore the critical role of defect and lattice engineering in tuning the functional response of correlated oxide systems.
Authors
- K. Manjunatha
- Chia‐Liang Cheng (ORCID: https://orcid.org/0000-0001-9572-4308)
- B. Daruka Prasad (ORCID: https://orcid.org/0000-0002-6485-3673)
- Sheng Yun Wu (ORCID: https://orcid.org/0000-0003-2750-5431)
- Ming-Kang Ho (ORCID: https://orcid.org/0009-0007-5032-677X)
- Hai Nguyen
- Shih-Lung Yu
- Meng-Chu Chen (ORCID: https://orcid.org/0009-0004-9452-1380)
- Yi-En Wu
- Tsung-Te Lin
- Yi-Ru Hsu
- Kai-Hsun Lin
- Hanumanthappa Nagabhushana (ORCID: https://orcid.org/0000-0001-7552-3373)
- Wei-Lun Li
- Tsu-En Hsu
- Wei-Che Lo
- Yun-Syuan Liang
- B. K. Monika
Institutions
- National Yang Ming Chiao Tung University (TW)
- National Taitung University (TW)
- National Tsing Hua University (TW)
- National Dong Hwa University (TW)
- Areté Associates (United States) (US)
- National Synchrotron Radiation Research Center (TW)
- Institut Technique de l'Aviculture (FR)
- Tumkur University (IN)
Publication Details
- Journal
- ACS Applied Materials & Interfaces
- Published
- 2026-04-21
- DOI
- https://doi.org/10.1021/acsami.5c26218
- Primary Topic
- Copper-based nanomaterials and applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science and Technology Council