Straightforward Donor Atom Switching: From P,C,P- to Various Y,C,Y-Pincer (Y = O, S, Se) Organotin(IV) Compounds and Cations
) X-ray diffraction analysis. The intramolecular P/Y → Sn interactions and their influence on the structures of complexes were analyzed in detail using NMR data and solid-state structures. The experiments were corroborated by a DFT study including NBO and AIM-analysis, which reveals the role of chalcogen centers in tuning the thermodynamic stabilization in the pincer complexes.
Authors
- Roman Jambor (ORCID: https://orcid.org/0000-0002-3639-7631)
- Zoltán Benkő (ORCID: https://orcid.org/0000-0001-6647-8320)
- Erik Kertész (ORCID: https://orcid.org/0000-0002-8817-8596)
- Aleš Růžička (ORCID: https://orcid.org/0000-0001-8191-0273)
- Zdeňka Růžičková (ORCID: https://orcid.org/0000-0003-0259-5557)
- Libor Dostál (ORCID: https://orcid.org/0000-0002-5982-1239)
- Richard Chlebík
Institutions
- University of Pardubice (CZ)
- Budapest University of Technology and Economics (HU)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-21
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c05899
- Primary Topic
- Molecular Junctions and Nanostructures
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Budapesti Műszaki és Gazdaságtudományi Egyetem
- Nemzeti Kutatási Fejlesztési és Innovációs Hivatal