Kinetics-controlled radical coupling on dual redox-active sites for selective formamide production
. This work demonstrates principles for orbital-mediated radical stabilization and kinetics-regulated radical-radical coupling, providing a paradigm for overcoming kinetic limitations for diverse radical-mediated catalytic reactions.
Authors
- Jieyuan Li (ORCID: https://orcid.org/0000-0003-3666-9796)
- Shujie Shen
- Fan Dong (ORCID: https://orcid.org/0000-0003-2890-9964)
- Jielin Wang (ORCID: https://orcid.org/0000-0002-0465-7531)
- Xin Li
- Chunling Zhang
Institutions
- University of Electronic Science and Technology of China (CN)
Publication Details
- Journal
- Nature Communications
- Published
- 2026-04-21
- DOI
- https://doi.org/10.1038/s41467-026-72215-z
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Institut de Ciències Fotòniques
- National Natural Science Foundation of China
- Natural Science Foundation of Sichuan Province