Substituent‐Controlled Reactivity of DMSO‐Derived Methyl and Methanesulfonyl Radicals in the N─H Functionalization of Arylamines
) affords the corresponding trideuteromethylated and trideuteromethanesulfonylated products with controllable selectivity, underscoring the method's versatility. It is worth noting that this represents the first DMSO-assisted method for N─H mesylation and methylation, both in general and specifically for arylamines.
Authors
- Palani Natarajan (ORCID: https://orcid.org/0000-0002-2859-271X)
- Önder Metin (ORCID: https://orcid.org/0000-0003-1622-4992)
- Burkhard Koenig (ORCID: https://orcid.org/0000-0002-6131-4850)
Institutions
- Koç University (TR)
- Panjab University (IN)
- University of Regensburg (DE)
Publication Details
- Journal
- Chemistry - A European Journal
- Published
- 2026-04-17
- DOI
- https://doi.org/10.1002/chem.71007
- Primary Topic
- Catalytic C–H Functionalization Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Türkiye Bilimsel ve Teknolojik Araştırma Kurumu