Enabling Fluoroalkyl-Sulfonylalkylation and Fluoroalkyl-Halogenation of Alkenes and Alkynes via Photoredox Catalysis
2-type displacement. Notably, the same reaction condition can be extended to achieve iodo- and bromo-trifluoromethylation via a halogen atom transfer mechanism by utilizing alkyl iodides and bromoacetyl bromides, respectively, in place of general alkyl bromides.
Authors
- Supuni I. N. Hewa Inaththappulige
- Harshvardhan Singh (ORCID: https://orcid.org/0000-0002-9071-1126)
- Ayush Acharya
- Nipuna D. D. Z. Agampodi
Institutions
- Pennsylvania State University (US)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-04-17
- DOI
- https://doi.org/10.1021/jacs.6c00567
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Pennsylvania State University
- NIH Office of the Director
- National Institute of General Medical Sciences