Pd(II)/Ce(III)‐Heterobimetallic Complex‐Catalyzed Decarbonylative Alkyne Annulation Reaction: Synthesis of Spiro‐Benzofuranindenones

The decarbonylation of 3‐hydroxy‐2‐phenyl‐chromenones and subsequent annulation with disubstituted alkyne in the presence of Pd(OAc) 2 (5.0 mol%) and Ce(OAc) 3 (10.0 mol%) provided an efficient route for the synthesis of spiro‐benzofuranindenones. This reaction could be used for the synthesis of wide range of spiro‐benzofuranindenones with good yields.

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Publication Details

Journal
European Journal of Organic Chemistry
Published
2026-04-16
DOI
https://doi.org/10.1002/ejoc.202501232
Primary Topic
Catalytic C–H Functionalization Methods
Type
article
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article

Pd(II)/Ce(III)‐Heterobimetallic Complex‐Catalyzed Decarbonylative Alkyne Annulation Reaction: Synthesis of Spiro‐Benzofuranindenones

Kongkona Gogoi, Bondana Bora, Sanjib Gogoi
European Journal of Organic Chemistry
Catalytic C–H Functionalization Methods
article

Pd(II)/Ce(III)‐Heterobimetallic Complex‐Catalyzed Decarbonylative Alkyne Annulation Reaction: Synthesis of Spiro‐Benzofuranindenones

Kongkona Gogoi, Bondana Bora, Sanjib Gogoi
article en

Abstract

The decarbonylation of 3‐hydroxy‐2‐phenyl‐chromenones and subsequent annulation with disubstituted alkyne in the presence of Pd(OAc) 2 (5.0 mol%) and Ce(OAc) 3 (10.0 mol%) provided an efficient route for the synthesis of spiro‐benzofuranindenones. This reaction could be used for the synthesis of wide range of spiro‐benzofuranindenones with good yields.

European Journal of Organic Chemistry
North East Institute of Science and Technology (IN), Academy of Scientific and Innovative Research (IN)
Openalex Percentile: Top 12%
Catalytic C–H Functionalization Methods
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