Phase Transformation and Magnetic Properties of Rapidly Solidified Mn-Al Alloys

Mn54Al46 alloys with τ-phase as their main component were successfully obtained in a reproducible processing window combining melt-spinning, annealing at intermediate temperatures (450 °C) and low-energy milling. The complete ε → τ phase transformation was driven by thermal decomposition of ε-phase and favored by high grain boundary density inherent to the melt-spun microstructure. An improved magnetic response of the melt-spun Mn54Al46 alloys was observed, as they exhibited saturation magnetization values between 80 and 90 emu/g, together with intrinsic coercivities around 2000 Oe and Curie temperatures between 640 and 648 K. Significant coercivity enhancement over 6000 Oe was predicted, by means of micromagnetic calculations, for alloys with grain size refinement below 100 nm. The efficient, single-step experimental phase transformation with no additional stabilizers for the τ-phase was explained in terms of microstructural features, whereas magnetic enhancement was attributed to lattice distortions promoted by the milling process. This integrated approach introduces a pathway to achieve τ-phase Mn-Al with tunable magnetic performance useful for applications.