Chlorosyl Nitrite (OClNO): An Elusive Intermediate in the Photochemistry of Nitryl Chloride
conformational conversion via quantum tunneling with further photoisomerization to ClONO has been observed. Our results underscore the role of OClNO as a potent intermediate in the atmospheric chlorine chemistry at low temperatures.
Authors
- Qi Yu (ORCID: https://orcid.org/0000-0002-2030-0671)
- Joseph S. Francisco (ORCID: https://orcid.org/0000-0002-5461-1486)
- G. Y. Zhang
- Tarek Trabelsi (ORCID: https://orcid.org/0000-0001-6258-7191)
- Yuyang Li (ORCID: https://orcid.org/0000-0002-5589-1029)
- Jiyang Yu
- Mingfei Zhou (ORCID: https://orcid.org/0000-0002-1915-6203)
- Xiaoqing Zeng (ORCID: https://orcid.org/0000-0003-4611-2094)
- Lina Wang (ORCID: https://orcid.org/0000-0002-9194-3527)
Institutions
- Fudan University (CN)
- California University of Pennsylvania (US)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-04-16
- DOI
- https://doi.org/10.1021/jacs.6c02450
- Primary Topic
- Atmospheric Ozone and Climate
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Ministry of Science and Technology of the People's Republic of China