Structural elucidation of a crystalline mannan from açaí (Euterpe oleracea Mart.) seeds

C CP/MAS solid-state NMR was employed to enable a comprehensive structural assessment. Solid-state NMR revealed the presence of a mannan I polymorph, with its crystalline nature further confirmed by X-ray diffraction. The identification of a highly crystalline linear mannan in açaí seeds provides structural insight relevant to the development of strategies aimed at reducing mannan crystallinity and designing specialized enzymatic cocktails for its efficient hydrolysis, thereby supporting the sustainable valorization of this abundant agro-industrial byproduct.

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Publication Details

Journal
International Journal of Biological Macromolecules
Published
2026-04-16
DOI
https://doi.org/10.1016/j.ijbiomac.2026.152093
Primary Topic
Seed Germination and Physiology
Type
article
Field-Weighted Citation Impact
0.00

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article

Structural elucidation of a crystalline mannan from açaí (Euterpe oleracea Mart.) seeds

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International Journal of Biological Macromolecules
Seed Germination and Physiology
article

Structural elucidation of a crystalline mannan from açaí (Euterpe oleracea Mart.) seeds

Ingrid Santos Miguez, Adriane R. Todeschini, Sylwia Głazowska, Carmen Lúcia de Oliveira Petkowicz, J. Junker, Francisco Felipe Bezerra, Ayla Sant’Ana da Silva, Paulo Antônio de Souza Mourão, Peter Ulvskov, Bodil Jørgensen
article en

Abstract

C CP/MAS solid-state NMR was employed to enable a comprehensive structural assessment. Solid-state NMR revealed the presence of a mannan I polymorph, with its crystalline nature further confirmed by X-ray diffraction. The identification of a highly crystalline linear mannan in açaí seeds provides structural insight relevant to the development of strategies aimed at reducing mannan crystallinity and designing specialized enzymatic cocktails for its efficient hydrolysis, thereby supporting the sustainable valorization of this abundant agro-industrial byproduct.

International Journal of Biological MacromoleculesVol. 362
Universidade Federal do Rio de Janeiro (BR), University of Copenhagen (DK), Instituto Nacional de Tecnologia (BR), Hospital Universitário Clementino Fraga Filho (BR), Fundação Oswaldo Cruz (BR), Universidade Federal do Paraná (BR)
Conselho Nacional de Desenvolvimento Científico e Tecnológico, Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro, Instituto Serrapilheira
Openalex Percentile: Top 22%
Seed Germination and Physiology
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