Application of the Fast Atmospheric Line-by-Line Code with Aerosol and Cloud Scattering (FALCAS) to TROPOMI Total Column Water Vapour Retrievals in the SWIR Band

Fast radiative transfer models are essential for the efficient processing of hyperspectral satellite data in trace gas retrievals, as full multi-stream radiative transfer simulations are computationally demanding. We present FALCAS (Fast Atmospheric Line-by-line Code with Aerosol and Cloud Scattering), a surrogate forward model combining line-by-line radiative transfer with the virtual isotropic scattering layer approximation adopted from FOCAL. FALCAS retains much of the accuracy of full multi-stream calculations while enabling rapid simulations. Previously validated against synthetic spectra from a discrete ordinate radiative transfer model, FALCAS is here applied to real measurements from the TROPOspheric Monitoring Instrument (TROPOMI) to retrieve total column water vapour (TCWV) in the shortwave infrared band around 2.3 μm. Retrieval results are compared to the operational TROPOMI Level-2 TCWV from the CH4 product. As this comparison is performed against an operational product from the same instrument, it represents an intercomparison rather than an evaluation against an independent reference dataset. FALCAS retrievals show a Pearson correlation coefficient greater than 0.99 with the operational data, and after empirical bias correction, the mean absolute bias across all regions is 1.45 mol m−2 (0.12% relative) and the mean RMSE is 39.24 mol m−2 (3.85% relative). These results demonstrate that FALCAS shows strong agreement with the operational TROPOMI Level-2 TCWV product, offering substantial computational advantages for large-scale processing.