Pore-Space-Partitioned Metal–Organic Frameworks with Acyclic Diene Linkers for C <sub>2</sub> H <sub>2</sub> /CO <sub>2</sub> Separation
capacity ratio of 3.2, an ideal adsorbed solution theory (IAST) selectivity of 5.80 (50:50 mixture), and a breakthrough separation window of 44 min/g, outperforming its stMA and bdc analogues. These results establish acyclic diene replacement as a distinct and effective isoreticular tuning strategy to optimize pore environments and sharpen the gas separation performance in partitioned MOFs.
Authors
- Yu Zhang (ORCID: https://orcid.org/0000-0001-5969-2388)
- Xiang Zhao
- Junqiang Chen (ORCID: https://orcid.org/0000-0001-7022-3099)
- Wenxuan Zhu (ORCID: https://orcid.org/0000-0002-4981-9258)
- Hanzi Zeng
- Xiaoyan Jiang
Institutions
- Wuhan University (CN)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-04-15
- DOI
- https://doi.org/10.1021/acs.inorgchem.6c01526
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Wuhan University