Peculiarities of Relativistic Effects in <sup>31</sup> P NMR Shielding Constants of Phosphines and Phosphine Chalcogenides

P NMR shielding constants of phosphines is substantially suppressed as compared to that in phosphine chalcogenides due to the presence of a phosphorus lone electron pair.

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Publication Details

Journal
Inorganic Chemistry
Published
2026-04-15
DOI
https://doi.org/10.1021/acs.inorgchem.6c00428
Primary Topic
Free Radicals and Antioxidants
Type
article
Field-Weighted Citation Impact
0.00
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article

Peculiarities of Relativistic Effects in 31 P NMR Shielding Constants of Phosphines and Phosphine Chalcogenides

Irina L. Rusakova, Yury Yu. Rusakov, Yuliya A. Nikurashina
Inorganic Chemistry
Free Radicals and Antioxidants
article

Peculiarities of Relativistic Effects in 31 P NMR Shielding Constants of Phosphines and Phosphine Chalcogenides

Irina L. Rusakova, Yury Yu. Rusakov, Yuliya A. Nikurashina
article en

Abstract

P NMR shielding constants of phosphines is substantially suppressed as compared to that in phosphine chalcogenides due to the presence of a phosphorus lone electron pair.

Inorganic ChemistryVol. 65(16)
A.E. Favorsky Irkutsk Institute of Chemistry (RU)
Openalex Percentile: Top 18%
Free Radicals and Antioxidants
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Peculiarities of Relativistic Effects in <sup>31</sup> P NMR Shielding Constants of Phosphines and Phosphine Chalcogenides — Irina L. Rusakova, Yury Yu. Rusakov, et al. · Inorganic Chemistry (2026) | TGRS Research Map | TGRS