Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes
elimination facilitated by a hydrogen acceptor, intramolecular C─H activation to form a cobaltacycle, and final reductive elimination to furnish the silacycle. Overall, this work establishes cobalt hydrides as a sustainable and effective alternative to noble metals for the synthesis of silacyclic architectures.
Authors
- Gilles Lemière (ORCID: https://orcid.org/0000-0002-6517-9967)
- Valentin Poirier (ORCID: https://orcid.org/0009-0007-4818-1444)
- Yongqiang Xu (ORCID: https://orcid.org/0009-0009-8640-1115)
- Julie Oble (ORCID: https://orcid.org/0000-0002-4002-255X)
- Marc Petit
Institutions
- Centre National de la Recherche Scientifique (FR)
- Sorbonne Université (FR)
- Institut Parisien de Chimie Moléculaire (FR)
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2026-04-14
- DOI
- https://doi.org/10.1002/anie.5584122
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- China Scholarship Council
- Centre National de la Recherche Scientifique