Discovery of confined two-dimensional Laves tiling in a magnesium alloy

Ca configuration confined to the (0001) basal plane of the Mg matrix, with a thickness of merely a single tiling layer (~4.62 Å), stabilized by adjacent Mg/Ca interfacial atomic layers. Theoretical calculations reveal that tensile strain in the surrounding matrix suppresses the diffusion of small-sized Al solutes, thereby inhibiting out-of-plane coarsening. Notably, prolonged thermal exposure leads to the formation of multi-configurational layered Laves structures assembled from these fundamental units. These findings elucidate the precipitation behavior in Mg-Al-Ca alloys and uncover a structurally confined Laves tiling motif, advancing our understanding of Laves phase formation and solute clustering in metallic systems.