Dual Photoredox/Brønsted Base-Catalyzed <i>syn</i> -Alkylcarboxylation of Bicyclo[1.1.0]butanes Using Malonates as Difunctional Reagents
-alkylcarboxylation of bicyclo[1.1.0]butanes (BCBs) with malonates, enabled by dual photoredox/Brønsted base catalysis. This method employs malonates as bifunctional reagents and accommodates a broad range of BCB derivatives, delivering cyclobutyl-fused 1,6-diesters in good to excellent yields.
Authors
- Hong‐Ping Deng (ORCID: https://orcid.org/0000-0003-4611-337X)
- Fei Xue (ORCID: https://orcid.org/0000-0002-9257-5076)
- Yuanhao Sun (ORCID: https://orcid.org/0000-0002-4809-809X)
- Pengfei Chen (ORCID: https://orcid.org/0000-0002-9549-5725)
- Yang Hong (ORCID: https://orcid.org/0009-0003-1687-7333)
- Chao-Yi Zheng
Institutions
- Nanjing Agricultural University (CN)
- Nanjing Forestry University (CN)
- Anqing Normal University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2026-04-15
- DOI
- https://doi.org/10.1021/acs.joc.6c00354
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Nanjing Agricultural University