Ru Nanowires for Effective Low‐Temperature CO <sub>2</sub> Methanation in the Aqueous Phase

selectivity at just 353 K while fully suppressing undesired RWGS activity. First-principles simulations reveal that aqueous solvation elevates the energy barriers for *CO desorption and dissociation relative to *HCOO hydrogenation, thereby shifting the reaction pathway decisively toward methanation. This work establishes a new strategy for robust, low-temperature Sabatier catalysis in water, offering a scalable route for power-to-gas applications under mild and sustainable conditions.

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Publication Details

Journal
Angewandte Chemie International Edition
Published
2026-04-14
DOI
https://doi.org/10.1002/anie.9230344
Primary Topic
Catalysts for Methane Reforming
Type
article
Field-Weighted Citation Impact
0.00

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article

Ru Nanowires for Effective Low‐Temperature CO 2 Methanation in the Aqueous Phase

Mufan Li, A Li, Junxian Gao, Jihan Zhou et al.
Angewandte Chemie International Edition
Catalysts for Methane Reforming
article

Ru Nanowires for Effective Low‐Temperature CO 2 Methanation in the Aqueous Phase

Mufan Li, A Li, Junxian Gao, Jihan Zhou, Z Wang, Weiwei Li, Xiaochen Zhang, Jia-Lan Chen, Mi Peng, Shiyun Li, Jisheng Xie, Chengyu Li, Ding Ma, Shou Qiu, Nanhong Xie, Mengzhu Li, Jiayun Zhao, Jin‐Xun Liu, Yuchen Deng
article en

Abstract

selectivity at just 353 K while fully suppressing undesired RWGS activity. First-principles simulations reveal that aqueous solvation elevates the energy barriers for *CO desorption and dissociation relative to *HCOO hydrogenation, thereby shifting the reaction pathway decisively toward methanation. This work establishes a new strategy for robust, low-temperature Sabatier catalysis in water, offering a scalable route for power-to-gas applications under mild and sustainable conditions.

Angewandte Chemie International Edition
Sinopec (China) (CN), University of Science and Technology of China (CN), Hefei University of Technology (CN), Beijing University of Technology (CN), Hefei National Center for Physical Sciences at Nanoscale (CN), Beijing National Laboratory for Molecular Sciences (CN), Academy of Mathematics and Systems Science (CN)
National Natural Science Foundation of China, Natural Science Foundation of Beijing Municipality, National Key Research and Development Program of China
Responsible consumption and production
Openalex Percentile: Top 27%
Catalysts for Methane Reforming
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