Mechanical Properties of Basalt–Polypropylene Hybrid Fiber-Reinforced Red Mud–Coal Metakaolin Geopolymer

Red mud-based composites show great potential in industrial solid waste utilization in response to the growing demand for low-carbon building materials. However, red mud-coal metakaolin geopolymers (RCGs) exhibit high brittleness and poor crack resistance, which limit their application in practical engineering. In order to improve the strength and toughness of RCGs, this study proposes a hybrid reinforcement strategy combining basalt fiber (BF) and polypropylene fiber (PPF). Effects of fiber length and fiber content on the mechanical properties of RCG were systematically investigated by orthogonal experimental design and response surface methodology (RSM). The microstructural characteristics were also analyzed using SEM, EDS, and XRD. Results show that fiber incorporation effectively enhances the mechanical properties and toughness of RCG, and BF length is the key factor influencing the strength of RCG. The optimal fiber ratio (BF: 11 mm, 0.23%; PPF: 6 mm, 0.20%) increases 9.52% of 28-day compressive strengths and 18.93% of 28-day flexural strengths. Microstructural analysis shows fibers bridging, interfacial stress transfer, and pull-out, which inhibit crack propagation. However, excessive fiber content may reduce matrix continuity. This manuscript provides a theoretical basis for optimizing red mud-based geopolymer composites and promotes the resource utilization of industrial solid waste.