Tailored Solvation Synergy in Phosphate Ester Electrolytes Toward High‐Voltage and Wide‐Temperature Sodium Metal Batteries

cells demonstrate over 1600 stable cycling at 4.5 V, sustain 800 cycles at 60°C, deliver high-rate capability up to 20 C, and maintain reliable operation at -20°C. This work offers new perspectives for designing safe SMBs that operate at high voltages and across a wide temperature range through synergistic solvation regulation and interface engineering.

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Publication Details

Journal
Small
Published
2026-04-14
DOI
https://doi.org/10.1002/smll.73371
Primary Topic
Advanced Battery Materials and Technologies
Type
article
Field-Weighted Citation Impact
0.00

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article

Tailored Solvation Synergy in Phosphate Ester Electrolytes Toward High‐Voltage and Wide‐Temperature Sodium Metal Batteries

Shimou Chen, Jihui Jing, Ying Xiao, Xinyu Wang et al.
Small
Advanced Battery Materials and Technologies
article

Tailored Solvation Synergy in Phosphate Ester Electrolytes Toward High‐Voltage and Wide‐Temperature Sodium Metal Batteries

Shimou Chen, Jihui Jing, Ying Xiao, Xinyu Wang, Tonghui Zhang, Haojie Xu
article en

Abstract

cells demonstrate over 1600 stable cycling at 4.5 V, sustain 800 cycles at 60°C, deliver high-rate capability up to 20 C, and maintain reliable operation at -20°C. This work offers new perspectives for designing safe SMBs that operate at high voltages and across a wide temperature range through synergistic solvation regulation and interface engineering.

Small
Beijing University of Chemical Technology (CN)
National Natural Science Foundation of China, Fundamental Research Funds for the Central Universities
Openalex Percentile: Top 18%
Advanced Battery Materials and Technologies
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