Asphalt Binder Modification with Hazelnut and Walnut Shells as Valued Antioxidant Sources: Effects on Rheological and Main Physicochemical Post-Oxidation Indicators

) and TPC than HS. The 3% treatments demonstrated optimal antioxidant efficacy, reducing long-term RAI by 14% and improving low-temperature flexibility by 3.8 °C (Fraass point -12.3 °C). However, MSCR revealed initial plasticizing effects decreasing elastic recovery (70%) and increasing non-recoverable compliance (Jnr) compromising unaged rutting resistance. Principal component analysis confirmed progressive diversification of aging-induced properties, evidencing complex multivariate trajectories. Ultimately, while nutshell derived phenolic modifiers provide effective concentration-dependent antioxidant protection, practical application requires optimization through targeted phenolic extraction, particle engineering, or elastomeric co-modification. Balancing aging resistance with high temperature stability remains essential for advancing these sustainable biomodification strategies in road infrastructure.