Cascade C─C/C─N Bonding for Acetamide Synthesis from Electrocatalytic CO <sub>2</sub> and Nitrate Coupling on CuCo Diatomic Sites
to stabilize on the catalytic surface via a favorable bridge adsorption configuration. And the electronic structure optimization promoted by interatomic electron interactions reduces the energy barriers for C─C and C─N bonding. This work achieves C─C─N bonding with ordered C─C and C─N coupling via diatomic sites, providing a novel strategy for the sustainable synthesis of acetamide.
Authors
- Guohua Zhao (ORCID: https://orcid.org/0000-0002-8693-1193)
- Jingui Zheng
- Siyi Xu (ORCID: https://orcid.org/0000-0002-8808-4282)
- Ruochen Yang (ORCID: https://orcid.org/0000-0001-9507-0607)
- Yi Zhou (ORCID: https://orcid.org/0000-0001-9610-4370)
- Xun Pan
- Lina Li (ORCID: https://orcid.org/0000-0003-4909-9796)
- Chao Miao
Institutions
- Tongji University (CN)
- Shanghai Advanced Research Institute (CN)
- Shanghai Institute of Applied Physics (CN)
Publication Details
- Journal
- Advanced Materials
- Published
- 2026-04-14
- DOI
- https://doi.org/10.1002/adma.73077
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- National Key Research and Development Program of China