Pd‐Catalyzed Allylic Arylation for Divergent Access to CF <sub>3</sub> ‐Functionalized Fluorenes and Dibenzofulvenes
We report a unified palladium‐catalyzed allylic arylation strategy for the divergent synthesis of CF 3 ‐functionalized fluorenes and dibenzofulvenes from CF 3 –π‐allyl‐Pd complexes. One pathway features the first α‐selective nucleophilic addition in CF 3 –π‐allyl‐Pd chemistry to yield CF 3 ‐fluorenes, while the other follows intramolecular Tsuji–Trost allylation and isomerization to generate CF 3 ‐dibenzofulvenes.
Authors
- Nagender Punna (ORCID: https://orcid.org/0000-0003-2761-6078)
- Chiliveru Priyanka
- Rami Sateesh
- Krishna Swaroop Desireddy
- Ramesh Vislavath
Institutions
- Indian Institute of Chemical Technology (IN)
- Academy of Scientific and Innovative Research (IN)
Publication Details
- Journal
- European Journal of Organic Chemistry
- Published
- 2026-04-13
- DOI
- https://doi.org/10.1002/ejoc.70457
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Science and Engineering Research Board