Temperature-Responsive Adsorption and Hydration Control of a Wide-Gradient Retarder in Oilwell Cementing (40 °C–120 °C)

The robustness of cement slurry performance under extreme vertical temperature gradients is critical for ensuring cementing operation safety in ultra-deep wells. This study systematically investigates the interfacial behavior and hydration control mechanisms of a temperature-sensitive composite retarder, TL-2. Adsorption analysis via Total Organic Carbon (TOC) reveals that TL-2 exhibits unique non-isothermal adsorption characteristics, where its adsorption capacity slightly increases with temperature (40 °C-90 °C). This behavior overcomes the conventional limitation of drastic adsorption decline at elevated temperatures and serves as the physicochemical foundation for its wide-temperature adaptability. Performance evaluations simulated wide-temperature gradient conditions: TL-2 provided stable thickening times at 120 °C, and samples developed adequate compressive strength after 3 days of curing at lower temperatures (40 °C and 60 °C) following an initial 120 °C thickening simulation. Microstructural characterization (XRD, MIP) further elucidates the strength evolution logic across the gradient: in the lower temperature zone (40 °C-60 °C), adequate strength is established within 3 days through precise induction period control; meanwhile, at 120 °C, matrix densification is enhanced by promoting the well-crystallized tobermorite formation. The results demonstrate that TL-2 achieves a refined "buffering" effect on the liquid-to-solid transition through dynamic interfacial regulation, exhibiting superior wide-temperature adaptability across extreme thermal gradients (40 °C-120 °C) and providing essential technical support for the operational safety of ultra-deep well cementing.