How Not to Do WLS Fitting in Calibration with Heteroscedastic Data

= 3-5 replicates. Further, of the four ways of weighting in the variance-function fitting, the iterative reweighting method gives the best results, in support of earlier findings.

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Publication Details

Journal
Analytical Chemistry
Published
2026-04-13
DOI
https://doi.org/10.1021/acs.analchem.5c07874
Primary Topic
Scientific Measurement and Uncertainty Evaluation
Type
article
Field-Weighted Citation Impact
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article

How Not to Do WLS Fitting in Calibration with Heteroscedastic Data

Joel Tellinghuisen
Analytical Chemistry
Scientific Measurement and Uncertainty Evaluation
article

How Not to Do WLS Fitting in Calibration with Heteroscedastic Data

Joel Tellinghuisen
article en

Abstract

= 3-5 replicates. Further, of the four ways of weighting in the variance-function fitting, the iterative reweighting method gives the best results, in support of earlier findings.

Analytical ChemistryVol. 98(16)
Vanderbilt University (US)
Peace, Justice and strong institutions
Openalex Percentile: Top 19%
Scientific Measurement and Uncertainty Evaluation
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